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57Fe Mössbauer probe of magnetic-electronic states under extreme conditions | LQMEC Synergy

Data do Evento: 
20/03/2024 - 15:00
Giovanni Hearne57Fe Mössbauer probe of magnetic-electronic states under extreme conditions
LQMEC Synergy com Prof. Giovanni Hearne (Dept. Physics, University of Johannesburg) 

20/03, 4ª feira, 15h. Ed. Principal, Auditório César Lattes ou via Zoom: sala 824 1511 3194, senha 011616

57 Fe Mössbauer spectroscopy (MS) is by now a well known local probe of the magnetic-electronic state of iron-based phases. It provides information on Fe valence, valence dynamics like charge transfer, local coordination changes, spin states and magnetic states. A more challenging, and therefore less common, application of the technique is 57 Fe MS under extreme conditions of high pressure. The above mentioned electronic states can then be probed in-situ as a function of pressure as a “tuning” parameter. I will briefly discuss the methodology of 57 Fe MS implemented under high pressure in the diamond anvil cell. Then I will exemplify its relevance in condensed matter physics, chemistry and geophysics contexts, by reviewing some of the studies mentioned in the references below.

1. “Interplay between H-bonding proton dynamics and Fe valence fluctuations in Fe 3 (PO 4 ) 2 (OH) 2 at high pressure”, G. Hearne, V. Ranieri, P. Hermet, et al., Phys. Rev. B 107, (2023) L060302. DOI: 10.1103/PhysRevB.107.L060302.
2. “Pressure-Induced Spin Crossover at Room Temperature in a Nanoporous Host-Guest Framework Structure”, Banele Vatsha, Rowan Goliath, and Giovanni Hearne, ChemPlusChem 86, (2021) 82–86. DOI:10.1002/cplu.202000557.
3. “Pressure-induced disruption of the local environment of Fe-Fe dimers in FeGa3 accompanied by metallization”, G. R. Hearne, S. Bhattacharjee, B. P. Doyle, et al., Phys. Rev. B 98, (2018) 020101(R). DOI: 10.1103/PhysRevB.98.020101
4. “Interplay between structural and magnetic-electronic responses of FeAl 2 O 4 to a megabar: Site inversion and spin crossover”, W. M. Xu, G. R. Hearne, S. Layek, et al., Phys. Rev. B 97, (2018) 085120. DOI: 10.1103/PhysRevB.97.085120.
 

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Data de Término: 
20/03/2024 - 16:00

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